Rose Floral Notes in Perfumery


Very little introduction is required for the Rose. Yet despite the fact that there are more than 10,000 species only 3 are used commercially for the production of Rose Oils and Absolutes.

Rosa damascena - a pink rose for the production of Rose Oil ( = Rose Attar, Rose Otto)
The greatest quality without parallel comes from the Valley of Roses Rosa Dolina  in Bulgaria. The next best is the Rose Oil Anatolian from Turkey.
Rosa centifolia - "Rose de Mai". for the production of Rose Absolute. Southern France produces the best quality followed by Morocco.
Rosa gallica - the oldest of the roses, cultivated in Egypt for the production of the oil and absolute.
 

        Analysis of the chemical composition of Rose reveals to us that the main components, known as the rose alcohols, are Citronellol, Geraniol, Nerol and Phenyl Ethyl Alcohol. The principle difference between the chemical composition of the oil vs. absolute is the loss of Phenyl Ethyl Alcohol from the oil  PEA dissolves in the distillation waters and therefore is alsmost absent from the oil. Other components are small amounts of the acetates of the Rose Alcohols, Eugenol and traces of Rose Oxide, Damascone and more than 300 other components.

        Not suprisingly a rose fragrance is usually founded on the Rose alcohols that are relatively cheap and readily available from aroma chemical suppliers. Their character as alcohols is such that they have smooth odours and are easily used. Modification comes in the form of the Rose Oxide and Damascone to give lift and radiance.

        Modification with green notes (esp. for a Tea Rose type) helps to impart a natural tone and the use of Clove Bud Oil A natural source of Eugenol gives depth and sweetness.

       Blending is not necessary per se but careful balancing of the rose alcohols carries out this function PEA is very hard to overdose but lacks diffusion.

       Fixation can be achieved with Trichloro methyl phenyl carbinyl acetate  (Rose Crystals, Roseacetal), Guaicwood Oil. Musks can be used as with all fragrance types but note that overdosing leads to sweet a character.
 
 

Rose
.    
............................................. % Remarks - e.g. overdose effect

Basics     

Phenyl Ethyl Alcohol 20-60 40-70% in the absolute / 1% in the oil
Citronellol 5-30  6% Abs./ 35% Oil 
Geraniol 5-25  3% Abs./ 20% Oil 
Nerol 0.1-2   1% Abs./ 6% Oil (Lemon character)
Rose Oxide 0.1-0.6 0.3% Abs./0.6% Oil -(harsh chemical)

  .

Modifiers     
Green -   
cis-3-Hexenol 0.1-0.3 cut grass green (too green) 
Phenyl Acetaldehyde   
Dimethyl Acetal
0.2-1 leafy green (harsh)

 

Spicy -  
Clove Bud Oil 0.5-1 (carnation/wallflower) 

    .

Blenders     
Rhodinol (ex Geranium Oil or Citronella) 5-20 smooth red-rosy natural 
alpha-Ionone 1-5  violet /iris
Phenyl Ethyl Alcohol 5-50  soft rose

  .

Fixatives     
Guaiacwood Oil 1-3  woody smokey earthy notes
Vetiveryl Acetate 1-5 velvety woody 
Rosacetol 1-5 metallic chemical note

.

Novel Effects    
Geranium Oil 1-3 Natural effect
Rose Oil 1-3 Fresh natural top note
Rose Absolute 1-3 Inncrease naturalness (earthy notes)
Aldehyde C.8 - C.12 0.01-0.2 Strengthen impact
beta-Damascone 0.05-0.3 diffusive (vine-fruit, plum)
Methyl Ionone 1-10 Blender (woody-earthy)
Citral 0.1-0.5 Top note - sharp (lemon-citrus)
Methyl Octine Carbonate 0.05-0.1 Violet greeness
Raspberry Ketone 0.1-0.5 Fruity note
Rose Alcohol acetates/esters 1-5 Increase freshness

.NB. These recommendations are for guidance and hints - do not be afraid to try as many different materials as possible

 
 
 
 
 

Rose Formulation Example
Phenyl Ethyl Alcohol   
Citronellol   
Geraniol 
Rose Oxide 
PADMA (Phenyl Acetaldehyde Dimethyl Acetal) 
cis-3-Hexenol 
Clove Bud Oil 
Methyl Ionone 
Geranium Oil 
Vetivert Oil 
Guaicwood Oil 
Rose Oil 
Rose de Mai Absolute  
Aldehyde C11 Undecylenic  
Galaxolide
45.00 
30.00 
15.00 
0.10 
0.50 
0.10 
0.50 
3.00 
1.40 
0.50 
1.00 
0.20 
0.10 
0.10 
2.50  
 

100.00